Thank you all for your help! I´m going to try it with a brick wall today.
@Alastair: Yes, I did notice that the plane of focus is curved, as I wasn´t able to get the center of the image and the periphery in focus at the same time. It´s even noticeable at 35mm, but it´s rather subtle compared to 18mm.
I always thought the speed booster was to blame here, but I´ve got a new one and the left side of the image is still not OK. I tried to adjust my previous SB, because it looked like the rear glass element was a bit skewed. It´s very loose if you don´t thighten the screw properly. Anyway, the adjustment didn´t pay. The left side was still too soft, while the right side was fine.
If only I had an optics free adapter for my Sigma, just to make sure that the lens is flawless.
UPDATE: A grid pattern should work fine to clearify the problem, although the effects gets more obvious if the focus is set to infinity. The 18mm image shows some reflections, as I had to use my screen as a brick wall replacement... The vignetting isn´t that strong in reality, I just wanted to emphasize it, maybe it tells you something I don´t know.
And here is what I see if I take a look at the BMPCC monitor. The focus peaking proves that the center seems to be shifted!? The camera was very well aligned to the monitor, yet the sharp center isn´t centered. This is exactly what I noticed with my fist speed booster and my first Sigma 18-35 too.