Hey
I read your novel

, and I discover lots of common experiences.
First of all, just not to forget, I think you shouldn't mind about the .mov extension, because if I remember well, the .dv extension captured by the good old iMovie was dropped a long time ago, which doesn't necessarily means what's wrapped inside isn't DV clips BTW...
I have a couple of ways to digitize footage because I wanted to have a solid WF I shouldn't have to think about each time the digitization occasion occurred, and I have about 3 ways now.
In case of a miniDV tape, for sure the simplest one is to connect the camcorder right to the Mac, and this can be done with a firewire input on a older mac, then the capture piece of software is almost secondary (I'd do it with FCP 7.0.3 I think, ust because I've been owning it for ages, but QT should be able as well).
Now yes, not only idealistic scenario happen, and what if the camcorder features no FW output ? More, what if no older Mac is around ? I decided to figure out how to use other routes which wouldn't be sloppy.
[This because not only miniDV were to be captured, but also PAL/SECAM VHS bigger tapes I'm regularly given, with all these vintage weddings and old family footage

]
Then I made some tests and discovered that these USB keys shaped digitizers do pretty good jobs, and even if I had preferred a direct S-Video route, even the CVBS and red and white audio analog inputs showed no major difference.
Here,
there,
anywhere, I did it the QT capture basic way you described and it worked great. I even discovered QT showed a 1080p capture option...
This was with an older mac at the capture end, but daisy chaining to USB should definitely work with a current one...

*MacMini M1 16 Go - Sonoma - Ext nvme SSDs on TB3 - 14 To HD in 2 x 4 disks USB3 towers
*Legacy MacPro 8core Xeons, 32 Go ram, 2 x gtx 980 ti, 3SSDs including RAID
*Resolve Studio everywhere, Fusion Studio too
*https://www.buymeacoffee.com/videorhin